Triethyl phosphonoacetate is a reagent for amoebic amalgam acclimated in the Horner-Wadsworth-Emmons acknowledgment (HWE) or the Horner-Emmons modification.
Triethyl phosphonoacetate can be added dropwise to sodium methoxide band-aid to adapt a phosphonate ylide. It has an acerb proton that can calmly be absent by a anemic base. If acclimated in an HWE acknowledgment with a carbonyl the consistent alkene formed is usually the E alkene, and is generated with accomplished regioselectivity.
Horner-Emmons-Wadsworth reagent afresh acclimated in the amalgam of chiral 2-methylcyclopropanecarboxylic acerbic from (S)-propylene oxide.
Reactant complex in:
• Horner-Wadsworth-Emmons reactions
• Intramolecular Heck-type cyclization and isomerizations
• Tsuji-Trost blazon reactions
• Intramolecular aryne-ene reactions
• Amalgam of aldehydes
from:Acridine Raw Material
Triethyl phosphonoacetate can be added dropwise to sodium methoxide band-aid to adapt a phosphonate ylide. It has an acerb proton that can calmly be absent by a anemic base. If acclimated in an HWE acknowledgment with a carbonyl the consistent alkene formed is usually the E alkene, and is generated with accomplished regioselectivity.
Horner-Emmons-Wadsworth reagent afresh acclimated in the amalgam of chiral 2-methylcyclopropanecarboxylic acerbic from (S)-propylene oxide.
Reactant complex in:
• Horner-Wadsworth-Emmons reactions
• Intramolecular Heck-type cyclization and isomerizations
• Tsuji-Trost blazon reactions
• Intramolecular aryne-ene reactions
• Amalgam of aldehydes
from:Acridine Raw Material
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